Analysis of Heavy Metal Content and Magnetic Mineral Morphology in River Sediments in Bajuin District, South Kalimantan

Syahdiannor Syahdiannor, Sudarningsih Sudarningsih, Tetti Novalina Manik, I Kadek Febry Anggi Pangestu, Gerald Tamuntu

Abstract


Bajuin District is a sub-district located in Tanah Laut Regency, South Kalimantan, where there is gold mining around the river basin. Gold mining activities are often a source of pollution, especially heavy metals, to the aquatic environment. This study aims to determine the content of heavy metals and the morphological characteristics of magnetic minerals in river sediments in the gold mining area. Heavy metal content measurement was carried out using X-Ray Fluorescence (XRF) instruments and magnetic mineral morphology was carried out using Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS) instruments. The results of measurements using XRF in river sediments found heavy metals Fe (2,495.40 – 4,395.83), Mn (51.40 – 70.60), Cr (18.60 – 107.93), Ni (8.03 – 21.87), V (9.33 – 12.77), Cu (5.53 – 13.50), and Zn (4.60 – 6.33) in ppm units. The results of magnetic mineral measurements based on SEM show that magnetic minerals are octahedral and irregular. Meanwhile, the results of EDS measurements show that the main constituent elements of magnetic minerals are Fe and O which indicate magnetic minerals. In addition, elements Al, Si, Sc, V, Cr, Zn, Au, and Hg were also found. The results of this study provide important implications for environmental conditions in Bajuin District, especially related to the potential for increased heavy metal pollution due to gold mining activities around the river.


Keywords


Sediments; heavy metals; magnetic minerals; pollution

Full Text:

PDF

References


Abbas, I. R. H., & Maulana, A. (2021). Petrology of ultramafíc Rocks from PT. Sebuku Iron Lateritic Ore (SILO) concession area and Its Effect on Ni and Fe in Sebuku Island, South Kalimantan, Indonesia. IOP Conference Series: Earth and Environmental Science, 921(1). https://doi.org/10.1088/1755-1315/921/1/012057

Arasteh, A., Khalesi, M. R., & Mohseni, M. (2023). Experimental and molecular modeling investigation on adsorption of gold cyanide complex onto the iron oxide and hydroxide minerals. Chemical Physics Letters, 830. https://doi.org/https://doi.org/10.1016/j.cplett.2023.140817

Arif, M., Moon, C. J., & Christidis, G. E. (1996). Garnierites from the ultramafic rocks in Swat , northwestern Pakistan Garnierites from the ultramafic rocks in Swat , northwestern Pakistan. Geol Bull, 29, 69–79.

Ayiwouo, M. N., Yamgouot, F. N., Ngueyep Mambou, L. L., Kingni, S. T., & Ngounouno, I. (2022). Impact of gold mining on the water quality of the lom river, Gankombol, Cameroon. Heliyon, 8(12), e12452. https://doi.org/10.1016/j.heliyon.2022.e12452

Bao, Z., Al, T., Bain, J., Shrimpton, H. K., Finfrock, Y. Z., Ptacek, C. J., & Blowes, D. W. (2022). Sphalerite weathering and controls on Zn and Cd migration in mine waste rock : An integrated study from the molecular scale to the field scale. Geochimica et Cosmochimica Acta, 318, 1–18. https://doi.org/10.1016/j.gca.2021.11.007

Bernadus, G. E., Polii, B., & Rorong, J. A. (2021). Dampak Merkuri Terhadap Lingkungan Perairan Sekitar Lokasi Provinsi Maluku Utara. Agri-SosioEkonomi Unsrat, 17, 599–610.

Bijaksana, S., Yunginger, R., Hafidz, A., & Mariyanto, M. (2019). Magnetic mineral characteristics, trace metals, and REE geochemistry of river sediments that serve as inlets to Lake Limboto, Sulawesi, Indonesia. Data in Brief, 26. https://doi.org/10.1016/j.dib.2019.104348

Boula, A., Laporte-magoni, C., Gunkel-grillon, P., Bour, O., Boula, A., Laporte-magoni, C., Gunkel-grillon, P., Bour, O., & Po-, N. S. (2022). Potential contamination of stream waters by ultramafic mining sediments : Identification of geochemical makers ( New Caledonia ) To cite this version : HAL Id : insu-03330547. Journal of Geochemical Exploration, 232. https://doi.org/10.1016/j.gexplo.2021.106879

Byrne, P., Taylor, K. G., Hudson-edwards, K. A., & Barrett, J. E. S. (2017). Speciation and potential long-term behaviour of chromium in urban sediment particulates. 2666–2676. https://doi.org/10.1007/s11368-016-1558-3

Canadian Environmental Protection Act.(1999). (n.d.). In Federal Environmental Quality Guidelines (Vanadium). https://www.canada.ca/en/environment-climate-change/services/evaluating-existing-substances/federal-environmental-quality-guidelines-selenium.html#toc0

Chandrasekaran, A., Senthil Kumar, C. K., Sathish, V., Manigandan, S., & Tamilarasi, A. (2021). Effect of minerals and heavy metals in sand samples of Ponnai river, Tamil Nadu, India. Scientific Reports, 11(1), 1–14. https://doi.org/10.1038/s41598-021-02717-x

Chen, M., Zhao, H., Fang, H., & Zhang, Y. (2017). Cross-Sectional Information on Pore Structure and Element Distribution of Sediment Particles by SEM and EDS. Scanning, 2017, 1–7. https://doi.org/10.1155/2017/9876935

Chen, Y., Liu, G., Zhou, C., Zhou, H., Wei, Y., & Liu, Y. (2023). The influence of gold mining wastes on the migration-transformation behavior and health risks of arsenic in the surrounding soil of mined-area. Frontiers in Earth Science, 10(January), 1–16. https://doi.org/10.3389/feart.2022.1068763

Choudhary, A., Khandelwal, N., Ganie, Z. A., & Darbha, G. K. (2024). Influence of magnetite and its weathering originated maghemite and hematite minerals on sedimentation and transport of nanoplastics in the aqueous and subsurface environments. Science of The Total Environment, 912.

Chrysochoou, M., Theologou, E., Bompoti, N., & Dermatas, D. (2016). Occurrence , Origin and Transformation Processes of Geogenic Chromium in Soils and Sediments. Current Pollution Reports, 224–235. https://doi.org/10.1007/s40726-016-0044-2

Ciobanu, C. L., Verdugo-ihl, M. R., Slattery, A., Cook, N. J., Ehrig, K., Courtney-davies, L., & Wade, B. P. (2019). Silician Magnetite: Si–Fe-Nanoprecipitates and Other Mineral Inclusions in Magnetite from the Olympic Dam Deposit, South Australia. Minerals, 9, 1–35.

Contaminated Sediment Standing Team. (2003). Consensus-Based Sediment Quality Guidelines Recommendations for Use & Application - Interim Guidance. In Interim Guidance (Issue December).

Evans, M. E., & Heller, F. (2003). Environment Magnetism Prinsiples and Aplication of Environmagnetics. Academic Press.

Fashola, M. O., Ngole-Jeme, V. M., & Babalola, O. O. (2016). Heavy metal pollution from gold mines: Environmental effects and bacterial strategies for resistance. International Journal of Environmental Research and Public Health, 13(11). https://doi.org/10.3390/ijerph13111047

Förstner, U., & Wittmann, G. T. W. (1983). Metal Pollution in the Aquatic Environment. In Springer-Verlag. Springer-Verlag. https://doi.org/10.1007/978-3-642-69385-4

Gafur, N. A., Sakakibara, M., Sano, S., & Sera, K. (2018). A case study of heavy metal pollution in water of Bone River by Artisanal Small-Scale Gold Mine Activities in Eastern Part of Gorontalo, Indonesia. Water (Switzerland), 10(11), 1–10. https://doi.org/10.3390/w10111507

Goldstein, J. I., Newbury, D. E., Michael, J. R., Ritchie, N. W. M., Scott, J. H. J., & Joy, D. C. (2018). Scanning Electron Microscopy and X-Ray Microanalysis (4th ed.). Spinger.

Golroudbary, S. R., Kraslawski, A., Wilson, B. P., & Lundström, M. (2022). Assessment of environmental sustainability of nickel required for mobility transition. Frontiers in Chemical Engineering, 4(January). https://doi.org/10.3389/fceng.2022.978842

González-pérez, I., González-jiménez, J. M., Yesares, L., & Acosta-vigil, A. (2024). Micro- to nano-sized solid inclusions in magnetite record skarn reactions. European Journal Of Mineralogy, 36, 925–941.

Hilson, G. (2002). The environmental impact of small-scale gold mining in Ghana. Geographical Journal, 168(1), 57.

Iizuka, M., Amano, A., & Itaki, T. (2025). MethodsX Accurate sampling of undisturbed top sediment from grab sampler collected using aluminum tube and stainless-steel containers for shallow and deep-sea applications ✩. MethodsX, 14(December 2024), 103213. https://doi.org/10.1016/j.mex.2025.103213

Ingri, J., Pekka, L., Dauvalter, V., Rodushkin, I., & Peinerud, E. (2011). Manganese redox cycling in Lake Imandra : impact on nitrogen and the trace metal sediment record. Biogeosciences Discuss, 8, 273–321. https://doi.org/10.5194/bgd-8-273-2011

Irsan, Male, Y. T., Ismail, I., Koto, S., Mangesa, R., Hadi, N., & Kasmawati. (2025). Logam Berat Merkuri (Hg): Penggunaannya pada Pertambangan Emas Skala Kecil (PESK) dan Dampaknya pada Ekosistem Perairan. Sleman: Penerbit Deepublish Digital.

Islam, M. S., Ahmed, M. K., Raknuzzaman, M., Habibullah -Al- Mamun, M., & Islam, M. K. (2015). Heavy metal pollution in surface water and sediment: A preliminary assessment of an urban river in a developing country. Ecological Indicators, 48, 282–291. https://doi.org/10.1016/j.ecolind.2014.08.016

Jurković, J., Babajić, E., Šarac, T. M., Kolar, M., & Kazlagić, A. (2020). Gold , Silver and Iron in Iron Oxy-hydroxide Precipitate Formed in. Journal of Mining and Environment (JME), 11(2), 334–346. https://doi.org/10.22044/jme.2020.9096.1811

Kabata-Pendias, A., & Pendias, H. (2001). Trace Element in Soils and Plants. In Biogeochemistry of Trace Elements. CRC Press: Boca Raton.

Katsuta, N., Umemura, A., Naito, S., Masuki, Y., Itayama, Y., Niwa, M., Sirono, S., Yoshida, H., & Kawakami, S. (2023). Heterogeneity effects in micro-beam XRF scanning spectroscopy of binary powdered mixtures and lake sediments. Spectrochimica Acta Part B: Atomic Spectroscopy, 210.

Kirana, K. H., Darmawan, R., Shafaria, M., Fitriani, D., Agustine, E., Tamuntuan, G. H., & Rosandi, Y. (2024). Magnetic Susceptibility and Heavy Metal Content of Sediments in the Upstream Citarik River. MSCEIS 2023, 256–264. https://doi.org/10.2991/978-2-38476-283-5_25

Latahir, A. Z., Wai, C. K., Yaacob, S. F. F. S., & Rahim, R. A. (2025). Exploring the elemental detection on portable XRF vs SEM-EDX in household alloy materials analysis. Microchemical Journal, 213.

Liu, Q., Roberts, A. P., Larrasoaa, J. C., Banerjee, S. K., Guyodo, Y., Tauxe, L., & Oldfield, F. (2012). Environmental magnetism: Principles and applications. Reviews of Geophysics, 50(4), 1–50. https://doi.org/10.1029/2012RG000393

Lo, M., Narulita, S., & Ickowitz, A. (2019). The relationship between forests and freshwater fish consumption in rural Nigeria. PLoS ONE, 14(6), 1–15. https://doi.org/10.1371/journal.pone.0218038

Luo, Y., Wang, N., Liu, Z., Sun, Y., & Lu, N. (2024). Characteristics and risk assessment of potentially toxic elements pollution in river water and sediment in typical gold mining areas of Northwest China. Scientific Reports, 14(1), 1–13. https://doi.org/10.1038/s41598-024-63723-3

Lv, P., Chang, S., Qin, R., Zhou, J., Wang, W., Hong, Q., Mei, J., & Yang, S. (2024). Different roles of FeS and FeS2 on magnetic FeSx for the selective adsorption of Hg2+ from waste acids in smelters: Reaction mechanism, kinetics, and structure-activity relationship. Chemosphere, 394. https://doi.org/https://doi.org/10.1016/j.chemosphere.2023.140917.

Mariyanto, M., Amir, M. F., Utama, W., Hamdan, A. M., Bijaksana, S., Pratama, A., Yunginger, R., & Sudarningsih, S. (2019). Heavy metal contents and magnetic properties of surface sediments in volcanic and tropical environment from Brantas River, Jawa Timur Province, Indonesia. Science of the Total Environment, 675, 632–641. https://doi.org/10.1016/j.scitotenv.2019.04.244

Mikulski, S. Z., Sadłowska, K., Wiszniewska, J., & Małek, R. (2022). Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland. Applied Sciences, 12.

Mistikawy, J. A., Mackowiak, T. J., Butler, M. J., Mischenko, I. C., Cernak, R. S., & Richardson, J. B. (2020). Chromium, manganese, nickel, and cobalt mobility and bioavailability from mafic-to-ultramafic mine spoil weathering in western Massachusetts, USA. Environmental Geochemistry and Health, 42(10), 3263–3279. https://doi.org/10.1007/s10653-020-00566-7

Oze, C. J., Laforce, M. J., Wentworth, C. M., Hanson, R. T., Bird, D. K., Coleman, R. G., & Bird, K. (2003). Chromium geochemistry of serpentinous sediment in the Willow core , Santa Clara County , CA. U.S. Geological Survey Open-File Report.

Shaheen, S. M., Alessi, D. S., Tack, F. M. G., Ok, Y. S., Kim, K. H., Gustafsson, J. P., Sparks, D. L., & Rinklebe, J. (2019). Redox chemistry of vanadium in soils and sediments: Interactions with colloidal materials, mobilization, speciation, and relevant environmental implications - A review. Advances in Colloid and Interface Science, 265, 1–13. https://doi.org/10.1016/j.cis.2019.01.002

Sojka, M., & Jaskuła, J. (2022). Heavy Metals in River Sediments: Contamination, Toxicity, and Source Identification—A Case Study from Poland. International Journal of Environmental Research and Public Health, 19(17). https://doi.org/10.3390/ijerph191710502

Sudarningsih, S. (2021). Analisis Logam Berat Pada Sedimen Sungai Martapura , Kalimantan Selatan Analysis of Heavy Metal Contents in Sediments from Martapura River , South Kalimantan. 18.

Sudarningsih, S., Bijaksana, S., Ramdani, R., Hafidz, A., Pratama, A., Widodo, W., Iskandar, I., Dahrin, D., Fajar, S. J., & Santoso, N. A. (2017). Variations in the concentration of magnetic minerals and heavy metals in suspended sediments from citarum river and its tributaries, West Java, Indonesia. Geosciences (Switzerland), 7(3). https://doi.org/10.3390/geosciences7030066

Sudarningsih, S., Pratama, A., Bijaksana, S., Fahruddin, F., Zanuddin, A., Salim, A., Abdillah, H., Rusnadi, M., & Mariyanto, M. (2023). Magnetic susceptibility and heavy metal contents in sediments of Riam Kiwa, Riam Kanan and Martapura rivers, Kalimantan Selatan province, Indonesia. Heliyon, 9(6), e16425. https://doi.org/10.1016/j.heliyon.2023.e16425

Tiwow, V. A., Rampe, M. J., & Sulistiawaty. (2022). Suseptibilitas Magnetik dan Konsentrasi Logam Berat Sedimen Sungai Tallo di Makassar. 22(1), 60–66.

Ureta, J. U., Ureta, J. C., Bower, L. M., Peoples, B. K., & Motallebi, M. (2024). The value of improving freshwater ecosystem services: South Carolina residents’ willingness to pay for improved water quality. Journal of Environmental Management, 353(September 2023), 120260. https://doi.org/10.1016/j.jenvman.2024.120260

Vaezihir, Abdorreza, Mahjoubi, Reza, Aghili, Somayeh, Mazaheri, Nader, Ahmadi, H., & Morteza. (2022). The Role of Natural Attenuation in the Decrease of Metal Concentration in a River Polluted by AMD Released from Sungun Mine ( NW of Iran ). IMWA, 535–540.

Vári, Á., Kozma, Z., Pataki, B., Jolánkai, Z., Kardos, M., Decsi, B., Pinke, Z., Jolánkai, G., Pásztor, L., Condé, S., Sonderegger, G., & Czúcz, B. (2022). Disentangling the ecosystem service ‘flood regulation’: Mechanisms and relevant ecosystem condition characteristics. Ambio, 51(8), 1855–1870. https://doi.org/10.1007/s13280-022-01708-0

Venier, M., Ziberna, L., Princivalle, F., Petrelli, M., Lughi, V., Logvinova, A., Sobolev, N. V, Turco, G., & Lenaz, D. (2022). Trace Elements in Chromian Spinels from Four Siberian Kimberlites. 12, 1–5.

Vespa, M., Wieland, E., Dähn, R., Grolimund, D., & Scheidegger, A. M. (2007). Determination of the elemental distribution and chemical speciation in highly heterogeneous cementitious materials using synchrotron-based micro-spectroscopic techniques. Cement and Concrete Research, 37, 1473–1482.

Wang, S., Liu, J., Li, J., Xu, G., Qiu, J., & Chen, B. (2020). Environmental magnetic parameter characteristics as indicators of heavy metal pollution in the surface sediments off the Zhoushan Islands in the East China Sea. Marine Pollution Bulletin, 150(March 2019), 110642. https://doi.org/10.1016/j.marpolbul.2019.110642

Yi, Y., Yang, Z., & Zhang, S. (2011). Ecological risk assessment of heavy metals in sediment and human health risk assessment of heavy metals in fishes in the middle and lower reaches of the Yangtze River basin. Environmental Pollution, 159(10), 2575–2585. https://doi.org/10.1016/j.envpol.2011.06.011

Zhang, C., Yu, Z. gang, Zeng, G. ming, Jiang, M., Yang, Z. zhu, Cui, F., Zhu, M. ying, Shen, L. qing, & Hu, L. (2014). Effects of sediment geochemical properties on heavy metal bioavailability. Environment International, 73, 270–281. https://doi.org/10.1016/j.envint.2014.08.010




DOI: http://dx.doi.org/10.20527/flux.v23i2.24794

Article Metrics

Abstract view : 222 times
PDF - 249 times

Refbacks

  • There are currently no refbacks.


Copyright (c) 2026 Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat

Creative Commons License
This work is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.

Association with:

Physical Society of Indonesia

Indexed by:

 

Creative Commons License
Jurnal Fisika FLux: Jurnal Ilmiah FMIPA Universitas Lambung Mangkurat is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.