Fabrikasi Kaca Tellurite Zinc Bismuth Dengan Teknik Melt Quenching
Abstract
Penelitian ini betujuan untuk memfabrikasi kaca Tellurite Zinc Bismuth (TZB) denga teknik melt quenching dan mendeskripsikan mengenai kondisi fisika (warna dan transparansi) kaca TZB. Bahan kaca yang digunakan dalam penelitian ini yakni serbuk Tellurite Oxide (TeO2) dengan kemurnian 99,99%, serbuk Zinc Oxide (ZnO) dengan kemurnian 99,9%, dan serbuk Bismut Oxide (Bi2O3) dengan kemurnian 99,9%. Komposisi yang digunakan adalah (80-x)TeO2-20ZnO-xBi2O3 dengan x=8,12,16 (mol%). Tahapan penelitian meliputi penyiapan alat dan bahan, pembuatan sampel dan karakterisasi sampel. Bahan dilebur di dalam furnace CARBOLITETM pada suhu 900oC selama 1 jam kemudian dituang ke dalam mold (cetakan) berukuran (3,5x2,5x0,5) cm yang telah dipanaskan pada suhu 300oC dan didinginkan secara natural cooling. Kaca TZB hasil fabrikasi seperti tampak transparan. Semua sampel kaca yang terbentuk berwarna kuning kehijauan (lime). Perlu dilakukan analisis lebih lanjut berupa UV-VIS untuk menentukan secara pasti pengaruh konsentrasi Bi2O3 sifat optis kaca TZB yang telah difabrikasi.
This research aims to fabricate Tellurite Zinc Bismuth (TZB) glass with melt quenching technique and to describe the physical condition (color and transparency) of TZB glass. The glass materials used in this research are Tellurite Oxide (TeO2) powder with 99.99% purity, 99.9% powder of Zinc Oxide (ZnO), and Bismuth Oxide (Bi2O3) powder with 99.9% purity. The composition used is (80-x) TeO2-20ZnO-xBi2O3 with x = 8.12,16 (mol%). Research stages include preparation of tools and materials, sample preparation and sample characterization. The material is melted in a CARBOLITETM furnace at 900°C for 1 hour then poured into a mold (sized) size (3.5x2.5x0.5) cm which has been heated at a temperature of 300oC and cooled by natural cooling. TZB glass fabrication results as it looks transparent. All glass samples are formed in greenish yellow (lime). Further analysis of UV-VIS is necessary to determine the exact effect of Bi2O3 concentration of the fabricated optical properties of glass TZB.
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Almeida, Rui. (2005). Optical dan Glass Photonic: Lec7. Structures of Glass III and Phase Separation. Book Chapter. Lehigh University: Bethlehem.
El-Mallawany, RAH. (2002). Tellurite Glasses Handbook: Physics Properties and Data. CRC Press: USA. pp.376.
Eraiah, B. (2010). Optical Properties of Lead–Tellurite Glasses doped with Samarium Trioxide. Journal Bullk Material Science. No.33(4): 391-394.
Konishi, T., Hondo, T., Araki, T., Nishio, K., Tsuchiya, T., Matsumoto, T., Suehara, S., Todoroki, Si., & Inoue, S. (2003). Investigation of Glass Formation and Color Properties in The P2O5–TeO2–ZnO System. Journal of Non-Crystalline Solids. Elsevier. No.324: 58–66.
Kundu, R.S., Dhankhar, S., Punia, R., Nanda, K., & Kishore, N. (2014). Bismuth modified physical, structural and optical properties of mid-IR transparent zinc boro-tellurite glasses. Journal of Alloys and Compounds. Elsevier. No.587: 66-73.
Manning, S. (2011). A Study of Tellurite Glass for Electro-Optic Optical Fibre Devices. Thesis Submitted for the Degree of PhD Faculty of Science: University of Adelaide. Australia.
Massera, J. (2009). Nucleation and Growth Behavior of Tellurite-based Glasses Suitable for MID-Infrared Applications. A Thesis Doctor of Philosophy of Material Science and Engeneering: Clemson University. United States.
Oo, H. M., Halimah M. K., & Yusoff, W.M.D.W. (2012). Optical Properties of Bismuth Tellurite based Glasses. International Journal of Molecular Science. No.13: 4623-4631.
Ozawa, T. (1999). Thermal Analysis-Review and Prospect. Thermochimica Acta. Elsevier. No.355: 35-42.
Rosmawati, B.H. (2008). Elastic, Optical And Thermal Properties Of TeO2-ZnO And TeO2-ZnO-AlF3 Glass Systems. Thesis Submitted for the Degree of PhD: University of Putra Malaysia. Malaysia.
Savelii, I., Jules, J.C., Gadret, G., Kibler, B., Fatome, J., El-Amraoui, M., Manikandan, N., Zheng, X., Desevedavy, F., Dudley, J.M., Troles, J., Brilland, L., Renversez, G., & Smektala, F. (2011). Suspended Core Tellurite Glass Optical fibers for Infrared Supercontinuum Generation. Optical Materials Journal. Elsevier. No.33: 1661–1666.
Sayyed, M.I. (2016). Bismuth modified shielding properties of zinc boro-tellurite glasses. Journal of Alloys and Compounds. Elsevier. No.688: 111-117.
Sharaf El-Deen, L.M., Al-Salhi, M.S., & Ekholy, M.M. (2008). IR and UV Spectral Studies for Rare Earths-doped Tellurite Glasses. Journal of Alloys and Compounds. Elsevier. No.465: 333-339.
Shelby, J.E. (2005). Introduction to Glass Science and Technology 2nd edition. The Royal Society Of Chemistry: USA. pp.202-221.
Suri, N., Bindra, K.S., Kumar, P., Kamboj, M.S., & Thangaraj, R. (2006). Thermal Investigations Ion Bulk Se(80-x) Te2O-Bix Chalcogenide Glass. Journal of Ovonic Research. Vol.2(6): 111-118.
Wahyudi, Marzuki, A., Cari & Pramuda, A. (2014). Analisis FTIR dan Minimum Loss pada Kaca Tellurite-Bismuth-Zinc-Plumbum untuk Aplikasi Fiber Optik Infrared. Jurnal Pendidikan Fisika Indonesia, Vol.10, No.1, hal 59-65.
Yakine, I., Chagraoui, A., Moussaoui, A., & Tairi, A. (2012). Synthesis And Characterization of New Amorphous And Crystalline Phases In Bi2O3-Ta2O5-TeO2 System. Journal Mater Environ Science. Vol3(4): 776-785.
Yamane, M., and asahara Y. (2000). Glasses for Phononics. Cambridge University Press: United Kingdom.
Yousef, E., Hotzel, H., & Rüssel. (2007). Effect of ZnO and Bi2O3 addition on linear and non-linear optical properties of tellurite glasses. Journal of Non-Cristaline Solids, Vol 353: 333-338.
DOI: http://dx.doi.org/10.20527/bipf.v6i2.4910
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