Characteristics of Chitosan from Chitin Deacetylation Using Different NaOH Concentration and Evaluation of Its Solubility in Liquid Smoke
Abstract
This research aimed to determine the effect of chitosan characteristics produced from the deacetylation of chitin with various concentrations of NaOH on its solubility in liquid smoke. Chitin produced from rajungan shell raw materials was deacetylated using 40% NaOH (K40%), 50% (K50%), and 60% (K60%). The resulting chitosan was then measured of its degree of deacetylation (DD), molecular weight (BM), and solubility in liquid smoke. The results showed that K40% had a DD of 56.99%, K50% had a DD of 72.86% and a BM of 149.1 kDa, also K60% had a DD of 82.87% and a BM of 102.6 kDa. The solubility of chitosan in 10% liquid smoke indicated that K40% was not dissolved, K50% was almost completely dissolved, and K60% was completely dissolved.
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Aberoumand, A., & Hoseinian, M. (2025). Extraction and characterization of chitosan obtained from shells of crab (Liocarcinus vernalis). Applied Food Research, 5(1), 100964. https://doi.org/10.1016/j.afres.2025.100964
Amitaye, A. N., Elemike, E. E., & Uzah, T. T. (2024). Multifarious techniques for resolving chitosan’s degree of deacetylation. Materials International, 6(2), 1–24. https://doi.org/10.33263/Materials62.016
Azizati, Z. (2019). Pembuatan dan karakterisasi kitosan kulit udang galah. Walisongo Journal of Chemistry, 2, 10–16. https://doi.org/10.21580/wjc.v3i1.3878
Cakasana, N., Suprijanto, J., & A. S. (2014). Aktivitas antioksidan kitosan yang diproduksi dari cangkang kerang simpling (Amusium sp.) dan kerang darah (Anadara sp.). Journal of Marine Research, 3, 395–404. https://doi.org/10.14710/jmr.v3i4.8360
Etminanrezaeieh, S., Rezazadeh, K., Jalilnejad, E., & Reza, R. (2025). Preparation and characterization of bio-waste derived chitosan hydroxyapatite pectin green biocomposite. Scientific Reports, 15, 24450. https://doi.org/10.1038/s41598-025-07588-0
Fadli, A., Drastinawati, O., Alexander, O., & F. H. (2017). Effect of chitin mass NaOH ratio and reaction time on characteristics of chitosan synthesized from waste of dried shrimp industry. Jurnal Sains Materi Indonesia, 18, 61–67. https://doi.org/10.17146/jsmi.2017.18.2.4166
Fearghail, F. O., Giltrap, M., O’Connor, C. O., & P. B. (2019). Improving extraction processes of crustacean chitin using solid state analytical techniques. International Journal of Applied Chemistry, 6, 23–30.
Ghanem, S. N., Marzouk, M. I., Tawfik, M. E., & Eskander, S. B. (2025). Spectroscopic approaches for structural analysis of extracted chitosan generated from chitin deacetylated for escalated periods. BMC Chemistry, 19, 214. https://doi.org/10.1186/s13065-025-01558-3
Junaidi, A. B., Apriyani, H., Abdullah, A., & Santoso, U. T. (2019). Fraksinasi dan karakterisasi asap cair dari kayu ulin (Eusideroxylon zwageri Teijsm. & Binn.) sebagai pelarut kitosan. Jurnal Riset Industri Hasil Hutan, 11, 53–64. https://doi.org/10.24111/jrihh.v11i2.4861
Junaidi, A. B., Irawati, U., & Santoso, U. T. (2021). Teknologi kitin dan kitosan: Definisi, preparasi dan karakterisasi. Banyubening Cipta Sejahtera.
Korampattu, L., Neha, G., & Paresh, L. D. (2024). Shell waste valorization to chemicals: Methods and progress. Green Chemistry, 26, 5601–5634. https://doi.org/10.1039/D3GC05177C
Niu, Y., & Hu, W. (2024). Preparation, characterization and application in environmental protection of low-molecular-weight chitosan: A review. Sustainable Environment Research, 34, 29. https://doi.org/10.1186/s42834-024-00236-8
Nurhikmawati, F., Manurung, M., & Laksmiwati, A. A. I. A. M. (2014). Penggunaan kitosan dari limbah kulit udang sebagai inhibitor keasaman tuak. Jurnal Kimia, 8, 191–197. https://doi.org/10.24843/JCHEM.2014.v08.i02.p08
Novikov, V. Y., Derkach, S. R., Konovalova, I. N., Dolgopyatova, N. V., & Kuchina, Y. A. (2023). Mechanism of heterogeneous alkaline deacetylation of chitin: A review. Polymers, 15(7), 1729. https://doi.org/10.3390/polym15071729
Periyannan, K., Selvaraj, H., Subbu, B., Pallikondaperumal, M., Karuppiah, P., Rajabathar, J., Al-Lohedan, H., & Thangarasu, S. (2023). Green fabrication of chitosan from marine crustaceans and mushroom waste: Toward sustainable resource utilization. Green Processing and Synthesis, 12(1), 20230093. https://doi.org/10.1515/gps-2023-0093
Ridhani, M. A., Vidyaningrum, I. P., Akmala, N. N., Fatihatunisa, R., Azzahro, S., & Aini, N. (2021). Potensi penambahan berbagai jenis gula terhadap sifat sensori dan fisikokimia roti manis: A review. Pasundan Food Technology Journal, 8, 61–68. https://doi.org/10.23969/pftj.v8i3.4106
Rochima, E. (2014). Study of utilization of crabs processing wastes and its application for chitosan-based healthy drink. Akuatika, 5(1), 71–82. https://jurnal.unpad.ac.id/akuatika/article/view/3707
Román-Doval, R., Torres-Arellanes, S. P., Tenorio-Barajas, A. Y., Gómez-Sánchez, A., & Valencia-Lazcano, A. A. (2023). Chitosan: Properties and its application in agriculture in context of molecular weight. Polymers, 15(13), 2867. https://doi.org/10.3390/polym15132867
Saïed, N., & Aïder, M. (2014). Zeta potential and turbidimetry analyses for the evaluation of chitosan phytic acid complex formation. Journal of Food Research, 3(2), 71–81. https://doi.org/10.5539/jfr.v3n2p71
Saravanan, A., Kumar, P., Yuvaraj, D., Jeevanantham, S., Aishwaria, P., Gnanasri, P. B., Gopinath, M., & Rangasamy, G. (2023). Polysaccharides from crustacean wastes and their environmental applications. Environmental Research, 221, 115330. https://doi.org/10.1016/j.envres.2023.115330
Vo, T. S., Chit, P. P., Hoang, T., Hoang, V. H., Dang, T. T., Vo, T. T. B. C., Park, Y., & Kim, K. (2025). Chitosan solubility in organic acid solutions under ultrasonication: A comparative perspective. International Journal of Biological Macromolecules, 331(Pt 1), 148394. https://doi.org/10.1016/j.ijbiomac.2025.148394
Wang, H., & Roman, M. (2023). Effects of chitosan molecular weight and degree of deacetylation on chitosan cellulose nanocrystal complexes and their formation. Molecules, 28(3), 1361. https://doi.org/10.3390/molecules28031361
Zuwanna, I., Riza, M., Aprilia, S., Syamsuddin, Y., Said, S., & Dewi, R. (2025). Investigation of characteristics whey protein isolate chitosan with silica addition in biocomposite film. International Journal of Technology, 16(1), 359–369. https://doi.org/10.14716/ijtech.v16i1.6335
DOI: http://dx.doi.org/10.20527/jstk.v20i1.25118
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Faculty of Mathematics and Natural Sciences
Universitas Lambung Mangkurat
Jl. A. Yani KM. 36 Banjarbaru 70714, Indonesia
Email: [email protected]
ISSN: 1411-1616 E-ISSN: 2549-8215
This work is licensed under a Creative Commons Attribution 4.0 International License .





