Photocatalytic Degradation of Naphthol Blue Black Using TiO2-Chitosan Catalyst Under Solar Energy

Utami Irawati, Taufiqur Rohman, Khairun Nisa

Abstract


Naphthol blue black (NBB) is an aromatic azo compound that is potentially carcinogenic and mutagenic. An alternative method of dealing with dye waste is photocatalysis. Photocatalysis is a combination of photochemical processes with the use of catalysts. The purpose of this study is to obtain data on the ratio of TiO2: Chitosan, which produces composites with the best ability, irradiation time and optimum dose of TiO2, which is effective in the process of photodegradation of NBB. The process of NBB photodegradation by chitosan beads and composites and chitosan irradiated with the best irradiation time on reducing NBB levels is for 360 minutes with a decrease in concentration of NBB more than 80%. Beads composite TiO2: Chitosan ratio of 5: 10 produces optimal ability. The optimum dose of composite beads in the NBB photodegradation process is 1 g composite / 100 mL solution.


Full Text:

PDF

References


Agustin, T., Prasetya, N.B.A. & Widodo, D.S., 2013. Sintesis Komposit TiO2-Karbon Aktif untuk Fotokatalisis Larutan Zat Warna Direct Blue 19 dan Ion Logam Pb2+ dan Cd2+ secara Simultan. Jurnal Kimia Sains dan Aplikasi, 16(3), pp.102-107 https://doi.org/10.14710/jksa.16.3.102-107

Ajmal, A., Majeed, I., Malik, R.N., Idriss, H. & Nadeem, M.A., 2014. Principles and Mechanisms of Photocatalytic Dye Degradation on TiO2 Based Photocatalysts: a comparative overview. Rsc Advances, 4(70), pp.37003-37026. https://doi.org/10.1039/C4RA06658H

Alam, M.M., Rahman, M.L. & Haque, M.Z., 2007. Extraction of Henna Leaf Dye and its Dyeing Effects on Textile Fibre. Bangladesh Journal of Scientific and Industrial Research, 42(2), pp.217-222. https://doi.org/10.3329/bjsir.v42i2.475

Balan, D.S. & Monteiro, R.T., 2001. Decolorization of Textile Indigo Dye by Ligninolytic Fungi. Journal of Biotechnology, 89(2-3), pp.141-145. https://doi.org/10.1016/S0168-1656(01)00304-2

Chekir, N., Benhabiles, O., Tassalit, D., Laoufi, N.A. & Bentahar, F., 2016. Photocatalytic Degradation of Methylene blue in Aqueous Suspensions Using TiO2 and ZnO. Desalination and Water Treatment, 57(13), pp.6141-6147. https://doi.org/10.1080/19443994.2015.1060533

Fathoni, I., 2016. Pemanfataan Bentonit Teknis Teknis Sebagai Adsorben Zat Warna. UNESA Journal of Chemistry, 5(3).

Garg, A., Mainrai, M., Bulasara, V.K. & Barman, S., 2015. Experimental Investigation on Adsorption of Amido black 10B Dye Onto Zeolite Synthesized from Fly Ash. Chemical Engineering Communications, 202(1), pp.123-130. https://doi.org/10.1080/00986445.2013.836636

Gimeno, O., García-Araya, J.F., Beltrán, F.J., Rivas, F.J. & Espejo, A., 2016. Removal of Emerging Contaminants from a Primary Effluent of Municipal Wastewater by Means of Sequential Biological Degradation-solar Photocatalytic Oxidation Processes. Chemical Engineering Journal, 290, pp.12-20. https://doi.org/10.1016/j.cej.2016.01.022

Hamdi, S., 2014. Mengenal Lama Penyinaran Matahari Sebagai Salah Satu Parameter Klimatologi. Berita Dirgantara, 15(1).

Harsini, M., Suyanto, Y.G.Y., Rhodifasari, L. & Darmokoesomo, H., 2017. Electrochemical Degradation of Naphthol AS-BO Batik Dyes. Journal of Chemical Technology and Metallurgy, 52(6), pp.1116-1122.

Haryono, M. F. D.. C. Liamita. N & Rostika, A., 2018. Pengolahan Limbah Zat Warna Tekstil Terdispersi dengan Metode Elektroflotasi. EduChemia (Jurnal Kimia dan Pendidikan), 3(1), pp.94-105. https://doi.org/10.30870/educhemia.v3i1.2625

Isfardiyana, S.H. & Sita, R. S., 2014. Pentingnya Melindungi Kulit dari Sinar Ultraviolet dan Cara melindungi Kulit dengan Sunblock Buatan Sendiri. Jurnal Inovasi dan Kewirausahan. 3(2), pp.126-133

Jawad, A.H., Mubarak, N.S.A., Ishak, M.A.M., Ismail, K. & Nawawi, W.I., 2016. Kinetics of photocatalytic decolourization of cationic dye using porous TiO2 film. Journal of Taibah University for Science, 10(3), pp.352-362. https://doi.org/10.1016/j.jtusci.2015.03.007

Joice, J.A.I., Sivakumar, T., Ramakrishnan, R., Ramya, G., Prasad, K.P.S. & Selvan, D.A., 2012. Visible active metal decorated titania catalysts for the photocatalytic degradation of Amidoblack-10B. Chemical engineering journal, 210, pp.385-397 https://doi.org/10.1016/j.cej.2012.08.103

Kabir, E., Kumar, P., Kumar, S., Adelodun, A.A. & Kim, K.H., 2018. Solar Energy: Potential and Future Prospects. Renewable and Sustainable Energy Reviews, 82, pp.894-900. https://doi.org/10.1016/j.rser.2017.09.094

Kevino. 2016. Pengolahan Limbah Tekstil dengan Teknologi Membran. Teknik Kimia. ITB, Bandung.

Khataee, A.R. & Kasiri, M.B., 2010. Photocatalytic Degradation of Organic Dyes in the Presence of Nanostructured Titanium Dioxide: Influence of the Chemical Structure of Dyes. Journal of Molecular Catalysis A: Chemical, 328(1-2), pp.8-26. https://doi.org/10.1016/j.molcata.2010.05.023

Khezrianjoo, S. & Revanasiddappa, H.D., 2013. Photocatalytic Degradation of Acid Yellow 36 Using Zinc Oxide Photocatalyst in Aqueous media. Journal of Catalysts, 2013. https://doi.org/10.1155/2013/582058

Kiswanti, E.A.D. & Pratapa, S., 2014. Sintesis Titanium Dioksida (TiO2) Menggunakan Metode Logam-Terlarut Asam. Jurnal Sains dan Seni ITS, 3(2), pp.B18-B21.

Kobya, M., Demirbas, E., Can, O.T. & Bayramoglu, M., 2006. Treatment of Levafix Orange Textile Dye Solution by Electrocoagulation. Journal of Hazardous Materials, 132(2-3), pp.183-188. https://doi.org/10.1016/j.jhazmat.2005.07.084

Licciulli, A. & Lisi, D., 2002. Self-cleaning glass. Universitá Degli Studi Di Lecce, Corso di laurea in Ingegneria dei Materiali, Scienza e Technologia dei Materiali Ceramici.(2001/2002),1, pp.1-29.

Naskhudin, Diantoro M., Kusumaatmaja. A. & Triyana. K., 2018. Study on Photocatalytic Properties of TiO2 Nanoparticle in various pH condition. In Journal of Physics: Conference Series (Vol. 1011, No. 1, p. 012069). IOP Publishing. https://doi.org/10.1088/1742-6596/1011/1/012069

Onder, S., Celebi, M., Altikatoglu, M., Hatipoglu, A. & Kuzu, H., 2011. Decolorization of naphthol blue black using the horseradish peroxidase. Applied biochemistry and biotechnology, 163(3), pp.433-443. https://doi.org/10.1007/s12010-010-9051-8

Pataya, S. A., 2016. Karakterisasi Lapisan Tipis Titanium Dioksida (TiO2) Yang Ditumbuhkan Dengan Metode Spin Coating Diatas Substrat Kaca.

Pathania, D., Gupta, D., Ala'a, H., Sharma, G., Kumar, A., Naushad, M., Ahamad, T. & Alshehri, S.M., 2016. Photocatalytic Degradation of Highly Toxic Dyes Using Chitosan-g-poly (acrylamide)/ZnS in Presence of Solar Irradiation. Journal of Photochemistry and Photobiology A: Chemistry, 329, pp.61-68. https://doi.org/10.1016/j.jphotochem.2016.06.019

Perdana, N.D., Wardhani, S. & Khunur, M.M., 2014. Pengaruh Penambahan Hidrogen Peroksida (H2O2) Terhadap Degradasi Methylene Blue Dengan Menggunakan Fotokatalis ZnO-Zeolit. Jurnal Ilmu Kimia Universitas Brawijaya, 2(2), pp.576-582.

Qamar, M., Saquib, M. & Muneer, M., 2005. Photocatalytic Degradation of Two Selected Dye Derivatives, Chromotrope 2B and Amido Black 10B, in Aqueous Suspensions of Titanium Dioxide. Dyes and Pigments, 65(1), pp.1-9. https://doi.org/10.1016/j.dyepig.2004.06.006

Rusydi, A.F., Suherman, D. & Sumawijaya, N., 2017. Pengolahan Air Limbah Tekstil Melalui Proses Koagulasi-Flokulasi dengan Menggunakan Lempung Sebagai Penyumbang Partikel Tersuspensi (Studi Kasus: Banaran, Sukoharjo Dan Lawean, Kerto Suro, Jawa Tengah). Arena Tekstil, 31(2), pp.105-114. https://doi.org/10.31266/at.v31i2.1671

Saraswathi, P. & Makeswari, M. 2018. Photocatalytic Degradation of Methylene Blue Dye Using Chitosan Silica Composite. Asian Journal of Chemistry, 30(7), pp.1603-1607. https://doi.org/10.14233/ajchem.2018.21273

Sastrawidana, I.D., Maryam, S. & Sukarta, I.N., 2012. Perombakan Air Limbah Tekstil Menggunakan Jamur Pendegradasi Kayu Jenis Polyporus Sp Teramobil Pada Serbuk Gergaji Kayu. Bumi Lestari Journal of Environment, 12(2), pp.382-389

Setyowati, M. S., & E. M. M. Putri., 2013. Kinetika Degradasi Fotokatalisis Pewarna Azoic dalam Limbah Industri Batik dengan Katalis TiO2. Jurnal Sains dan Seni Pomits. 2(1), pp.1-5

Sucahya, T.N., Permatasari, N. & Nandiyanto, A.B.D., 2016. Fotokatalis Untuk Pengolahan Limbah Cair. Jurnal integrasi proses, 6(2), pp. 1-15.

Wibowo, E.A.P., Aji, N.R., Ujiningtyas, R., Mayasari, T. & Widiarti, N., 2016. Fotokatalis TiO2/Kitosan dan TiO2/Bentonit sebagai Penjernih Air Embung di Lingkungan Unnes. Jurnal Sains dan Teknologi, 5(2), pp.807-812. https://doi.org/10.23887/jstundiksha.v5i2.8580

Xu, J.C., Lu, M., Guo, X.Y. & Li, H.L., 2005. Zinc Ions Surface-doped Titanium Dioxide Nanotubes and its Photocatalysis Activity for Degradation of Methyl Orange in Water. Journal of Molecular Catalysis A: Chemical, 226(1), pp.123-127. https://doi.org/10.1016/j.molcata.2004.09.051

Zhao, H., Jiang, D., Zhang, S., Catterall, K. & John, R., 2004. Development of a Direct Photoelectrochemical Method for Determination of Chemical Oxygen Demand. Analytical chemistry, 76(1), pp.155-160. https://doi.org/10.1021/ac0302298

Zhao, X., Xiao, G., Zhang, X., Su, H. & Tan, T., 2012. The Effect of Ni2+ and Cu2+ on the Photocatalytic Degradation of Dyes by the Chitosan-TiO2 Complex. Applied biochemistry and biotechnology, 168(1), pp.183-197. https://doi.org/10.1007/s12010-011-9407-8

Zhu, H., Jiang, R., Xiao, L., Chang, Y., Guan, Y., Li, X. & Zeng, G., 2009. Photocatalytic Decolorization and Degradation of Congo Red on Innovative Crosslinked Chitosan-nanoCdS Composite Catalyst Under Visible Light Irradiation. Journal of Hazardous Materials, 169(1-3), pp.933-940. https://doi.org/10.1016/j.jhazmat.2009.04.037

Zubieta, C.E., Messina, P.V., Luengo, C., Dennehy, M., Pieroni, O. & Schulz, P.C., 2008. Reactive dyes remotion by porous TiO2-Chitosan Materials. Journal of Hazardous materials, 152(2), pp.765-777. https://doi.org/10.1016/j.jhazmat.2007.07.043




DOI: http://dx.doi.org/10.20527/jstk.v18i2.21809

Article Metrics

Abstract view : 168 times
PDF - 181 times

Refbacks

  • There are currently no refbacks.


Department of Chemistry
Faculty of Mathematics and Natural Sciences
Universitas Lambung Mangkurat
Jl. A. Yani KM. 36 Banjarbaru 70714, Indonesia
Email: [email protected]
ISSN: 1411-1616 E-ISSN: 2549-8215

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License .